Friday, 4 September 2020

Ionizing Radiation, an Instrument in Chemical Evolution Studies: Scope and Perspectives

 

  • E Y Aguilar-Ovando
    Institute of Nuclear Sciences, National Autonomous University of Mexico (UNAM), 04510 Mexico City, Mexico
  • A Negron-Mendoza
    Institute of Nuclear Sciences, National Autonomous University of Mexico (UNAM), 04510 Mexico City, Mexico
  • M L Ramirez-Vazquez
    Institute of Nuclear Sciences, National Autonomous University of Mexico (UNAM), 04510 Mexico City, Mexico; Postgraduate in Earth Sciences, National Autonomous University of Mexico (UNAM)
  • R C Acosta-Fernandez
    Chemistry Faculty, National Autonomous University of Mexico (UNAM)
Keywords: Chemical Evolution, Keto Acids, Ionizing Radiation

Abstract

The study of synthesis and stability of molecules in different environments it’s been part of chemistry evolution and origin of life studies for more than 70 years. Various kinds of ionizing radiation have been analyzed as possible sources of energy for the transformations undergone by the first organic molecules. Now experimental and computational simulation approaches continue with different groups of organic molecules, in search for more information that help us to understand and reconstruct somehow the mechanisms that took place on early Earth and space. In that line, this paper presents first approach of keto acids stability to ionizing radiation, an interesting group of molecules involved in the Krebs cycle and glycolysis. Preliminary results obtained by HPLC/UV analysis of irradiating aqueous solutions of 5 keto acids ranging from 3 to 6 carbons with a 60Co gamma ray source, using doses up to 53 kGy, show different stabilities and a general tendency of shifting the keto-enol equilibrium to the enol tautomer before decomposition.

References

L. Garzon and M. Garzon, Origins Of Life And Evolution of Biospheres 31, (2001).

J. O’Donnell and D. Sangster, Principles of Radiation Chemistry (Edward Arnold, London, 1970), p. 176.

G. Cooper, C. Reed, D. Nguyen, M. Carter and Y. Wang, Proceedings Of The National Academy Of Sciences 108, (2011).

A. Lehninger, D. Nelson and M. Cox, Principles Of Biochemistry, 6th ed. (W.H. Freeman, New York, 2013).

Z. Martins, Elements 7, (2011).

M. Sephton, Astronomy & Geophysics 45, (2004).

I. Draganic, Z. Draganic and J. Adloff, Radiation And Radioactivity On Earth And Beyond (CRC Press, Boca Raton, 1993).

R. Navarro-Gonzalez, A. Negron-Mendoza and G. Albarran, Journal Of Chromatography A 587, (1991).

A. Negron-Mendoza, G. Albarran and S. CastilloRojas, Journal of Radio analytical and Nuclear Chemistry 160, (1992). 

Issue
 
 
How to Cite
E Y Aguilar-Ovando; A Negron-Mendoza; M L Ramirez-Vazquez; R C Acosta-Fernandez. Ionizing Radiation, an Instrument in Chemical Evolution Studies: Scope and Perspectives. J. Nucl. Phy. Mat. Sci. Rad. A. 2018, 6, 99-101.
 

 

 

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