Abstract
The stability of biologically important molecules, such as amino
acids, being subjected to high radiation fields is relevant for chemical
evolution studies. Bodies of water were very important in the primitive
Earth. In these bodies, the presence of dissolved salts, together with
organic molecules, could influence the behavior of the systems in
prebiotic environments.
The objective of this work is to examine the
influence of sodium chloride on the stability of the amino acid glycine
when subjected to high radiation doses. The analysis of the irradiated
samples was followed by HPLC coupled with a UV-VIS detector. The results
show that glycine in aqueous solutions (without oxygen) decomposed
around 90% at a dose of 91 kGy. In the presence of salts, up to 80% of
the amino acid was recovered at the same dose. Laboratory simulations
demonstrate a protective role for sodium chloride (specifically the
chloride ion) to glycine against an external source of ionizing
radiation.
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